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Castor-bean acid lipase catalysed hydrolysis of triacylglycerols does not involve C-2 → C-1,3 transacylation

Artículo académico Persona
Researcher in Centre for Environment and Health, Department of Epidemiology and Biostatistics, Imperial College London, London, England.

Enfoque geográfico

Abstracto

  • The hydrolysis of a series of triacylglycerol analogs catalysed by castor-bean acid lipase was studied at 30° and pH 4.20. Iso-propyl esters underwent lipolysis, thus refuting the mechanistic proposition that hydrolysis at C-2 in triacylglycerols occurs via a slow transfer of the acyl moiety from C-2 to either C-1 or C-3, followed by enzymic hydrolytic action.

fecha de publicación

  • 1985